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Dr. Brolo's Publication List 2012
86. C. Escobedo, A. G. Brolo, R. Gordon, and D. Sinton, 2012, “Optofluidic Concentration: Plasmonic Nanostructure as Concentrator and Sensor”, NanoLetters, 12, 1592−1596, Reprint - PDF
85. M. Fan, P. Wang, C. Escobedo, D. Sinton and A. G. Brolo, 2012, ”Surface-enhanced Raman scattering (SERS) optrodes for multiplexed on-chip sensing of nile blue A and oxazine 720”, Lab on a Chip,12, 1554, Reprint - PDF
84. G. F. S. Andrade, Q. Min, .R. Gordon, and A. G. Brolo, 2012, ”Surface-Enhanced Resonance Raman Scattering on Gold Concentric Rings: Polarization Dependence and Intensity Fluctuations”, Journal of Physical Chemistry C, 116, 2672−2676. Reprint - PDF
83. A. Lee, A. Ahmed D. P. dos Santos, N.Coon, J. Il Park, R. Gordon, A. G. Brolo, and E. Kumacheva, 2012, Side-by-Side Assembly of Gold Nanorods Reduces Ensemble-Averaged SERS Intensity”,, Journal Physical Chemistry C, 116, 5538−5545 - Reprint - PDF 2011 82. S. F. Romanuik, S.M. Grist, B. L. Gray, D. Hohertz, K. L. Kavanagh, N. Gulzar, J. K. Scott, R. Nirwan, C. Hui, A. G. Brolo, R. Gordon,, 2011, “Detecting Antibodies Secreted by Trapped Cells Using Extraordinary Optical Transmission”, IEEE Sensors Journal, 11, 2732-2739, Reprint - PDF
81. Q Matthews, A Jirasek, J J Lum and A G Brolo, 2011, “Biochemical signatures of in vitro radiation response in human lung, breast and prostate tumour cells observed with Raman spectroscopy”, Physics in Medicine and Biology, 56, 6839, Reprint - PDF
80. C. M. S. Izumi, M. Moffitt and A. G. Brolo, 2011, ”Statistics on Surface-Enhanced Resonance Raman Scattering from Single Nanoshells, Journal of Physical Chemistry C,115, 19104–19109, Reprint - PDF
79. M. Das, D. Horertz, R. Nirwan, A. G. Brolo, K. L. Kavanagh and R. Gordon, 2011, ”Improved Performance of Nanohole Surface Plasmon Resonance Sensors by the Integrated Response Method, IEEE Photonics Journal, 3, 441 - 449. Reprint - PDF
78. A. Lee, G. F. S. Andrade, A. Ahmed, M. L. Souza, N. Coombs, E. Turmarkin, L. Liu, R. Gordon, A. G. Brolo and E. Kumacheva, “Probing Dynamic Generation of Hot-Spots in Self-Assembled Chains of Gold Nanorods by Surface-Enhanced Raman Scattering”, 2011, The Journal o the American Chemical Society, 133, 7563 - 7570 - Reprint - PDF
77. M. Fan, G. F. S. Andrade and A. G. Brolo, “A review on the fabrication of substrates for surface enhanced Raman spectroscopy and their applications in analytical chemistry”, 2011, Analytica Chimica Acta, 693, 7-25, Reprint - PDF
76. J. Ferreira, A. G. Brolo and E. M. Girotto, “Probing speciation inside a conducting polymer matrix by in situ spectroelectrochemistry”, 2011, Electrochimica Acta, 56, 3101 - 3107 - Reprint - PDF
75. M. Fan, M. Marechal, A. Finn, D. A. Harrington, A. G. Brolo, “Layer-by-Layer Characterization of a Model Biofuel Cell Anode by (in Situ) Vibrational Spectroscopy”, 2011, Journal of Physical Chemistry C, 115, 310-315 - Reprint - PDF
74. Q. Matthews, A. G. Brolo, J. Lum, X. Duan and A. Jirasek, “Raman spectroscopy of single human tumour cells exposed to ionizing radiation in vitro”, 2011, Physics in Medicine and Biology, 56, 19-38. Reprint - PDF
73. D. P. dos Santos, G. F. S. Andrade, A. G. Brolo, M. L. A. Temperini, “Fluctuations of the Stokes and anti-Stokes surface-enhanced resonance Raman scattering intensities in an electrochemical environment”, 2011, Chemical Communications, 47, 7159-7160 - Reprint - PDF
72. S. F. Romanuik; S. M. Grist; M. Haq ; B. L. Gray, N. Gulzar, J. K. Scott, D. Hohertz, K. L. Kavanagh, R. Nirwan, C. Hui, A. G. Brolo, “Microfluidic Trapping of Antibody-secreting Cells” 2011, Journal of Medical and Biomedical Engineering, 31, 121-127 - Reprint - PDF 2010 71. C. Escobed, A. G. Brolo, R. Gordon, D. Sinton, “Flow-Through vs Flow-Over: Analysis of Transport and Binding in Nanohole Array Plasmonic Biosensors”, 2010, Analytical Chemistry, 82, 10015-10020 - Reprint - PDF
70. J. R. Anema and A. G. Brolo, 2010, “Use of polarization-dependent SERS from scratched gold films to monitor the electrochemically-driven desorption and readsorption of cysteine”, Journal of Electronalytical Chemistry, 649, 159-163. Reprint - PDF
69. J. W. Menezes, J. Ferreira, M. J. L. Santos, L. Cescato, A. G. Brolo, 2010, “Large-Area Fabrication of Periodic Arrays of Nanoholes in Metal Films and Their Application in Biosensing and Plasmonic-Enhanced Photovoltaics”, Advanced Functional Materials, 20, 3918-3924 - Reprint - PDF
68.Q. Matthews, A. Jirasek, J. Lum, X. Duan, A. G. Brolo, 2010, “Variability in Raman Spectra of Single Human Tumor Cells Cultured in Vitro: Correlation with Cell Cycle and Culture Confluency”, Applied Spectroscopy, 64 (8), 871-887 - Reprint - PDF
67. M. Fan, M. L. Andrade, M. Thompson, A. G. Brolo, 2010, "Silver nanoparticles on a plastic platform for biosensing", Analytical Chemistry, 82, 6350 - 6352 - Reprint - PDF
66. M. Fan and A. G. Brolo, 2010, “Multilayer Silver Nanoparticles Modified Optical Fiber Tip for High Performance SERS Remote Sensing”, Biosensors and Bioelectronics, 25, 2270 - 2275 - Reprint - PDF
65. . J. R. Anema, A. G. Brolo, A. Felten and C. Bittencourt, 2010, “Surface-enhanced Raman scattering from polystyrene on gold clusters.”, Journal of Raman Spectroscopy, 41, 745–751, Reprint - PDF
64. R. Gordon, A. G. Brolo, D. Sinton, and K. L. Kavanagh, 2010, “Optical Properties of Hole-Arrays in Metal Films”, Lasers and Photonics Reviews, 4, 311 - 335. Reprint - PDF
2009
62 D. P. dos Santos, G. F.S. Andrade, M. L. A. Temperini, A. G. Brolo, 2009, “Electrochemical Control of the time-dependent intensity fluctuations in surface-enhanced Raman scattering (SERS)”, Journal of Physical Chemistry C, 113,17737 - 17744, Reprint - PDF
61. P. L. Anto, R. J. Anto, H. T. Varghese, C. Y. Panicker, D. Philip, A. G. Brolo, 2009, “FT-IR, FT-Raman and SERS spectra of anilinium sulfate”, Journal of Raman Spectroscopy, 40, 1810 – 1815, Reprint - PDF
60. F. Eftekhari,C. Escobedo, J. Ferreira, X. Duan, E. M. Girrotto, A.G. Brolo, R. Gordon, and D. Sinton, 2009, “Nanoholes as nanochannels: flow-through plasmonic sensing arrays”, Analytical Chemistry, 81, 4308–4311, Reprint - PDF
59. M. Fan, and A. G. Brolo , 2009, “Silver nanoparticles self assembly as SERS substrates with near single molecule detection limit ”, Phys. Chem. Chem. Phys., 11, 7381 - 7389, Reprint - PDF
58. G. V. M. Jacintho, A. G. Brolo, P. Corio, P. A. Z. Suarez and J. C. Rubim, 2009, Structural Investigation of MFe2O4 (M = Fe, Co) Magnetic Fluids, Journal of Physical Chemistry C, 113, 7684–7691, Reprint - PDF
57. C. J. Addison, S. O. Konorov, A. G. Brolo,M. W. Blades and R. F.B. Turner, 2009, “Tuning Gold Nanoparticle Self-Assembly for Optimum Coherent anti-Stokes Raman Scattering and Second Harmonic Generation Response”, Journal of Physical Chemistry C, 113, 3586 - 3592 - Reprint - PDF
56. E. A. Batista, D. P. dos Santos, G. F.S. Andrade, A. C. Sant’Ana, A. G. Brolo, M. L. A. Temperini, 2009 “Using polycarbonate membranes as templates for the preparation of Au nanostructures for SERS”, Journal of Nanosciences and Nanotechnology, 9, 3233 - 3238 - Reprint - PDF
55. M. J. L. Santos, J. Ferreira, M. Rahman, A. G. Brolo, R. Gordon and E. M. Girotto, (2009), “Attomolar protein detection using in-hole SPR”, Journal of the American Chemical Society, 131, 436-437. Reprint - PDF
54. G. Hager and A. G. Brolo. 2009, “Protonation and deprotonation of cysteine and cystine monolayers probed by impedance spectroscopy”, Journal of Electroanalytical Chemistry, 625, 109 - 116. Reprint - PDF
2008
53. Q. Min, M. J. L. Santos, E. M. Girotto, A. G. Brolo, R. Gordon, 2008, “Localized Raman Enhancement from a Double-Hole Nanostructure in a Metal Film”, Journal of Physical Chemistry C, 112, 15098-15101. Reprint - PDF
52. J. Anema, P. Marthandam, R. Gordon and A. G. Brolo, 2008 “Enhanced Raman Scattering from Nanoholes in a Copper Film”, Journal of Physical Chemistry C, 112, 17051–17055 - Reprint - PDF
51. P. Marthandam, A. G. Brolo, D. Sinton, K. L. Kavanagh, M. Moffitt and R. Gordon, (2008), “Nanoholes in metals with applications to sensors and spectroscopy”, invited review - International Journal of Nanotechnology, 5, 1058 - 1081 50. F. Eftekhari, R. Gordon, J. Ferreira, A. G. Brolo, and D. Sinton, 2008, “Polarization-dependent sensing of a self-assembled monolayer using biaxial nanohole arrays”, Applied Physics Letters, 92, 253103. Reprint - PDF
49. G. F.S. Andrade, A. G. Brolo, and M. L.A. Temperini, 2008, “Comparison of SERS performances of Co and Ni ultra-thin films over Silver to electrochemically activated Co and Ni electrodes”, Journal of Physical Chemistry C, 112, 15348-15355 - Reprint - PDF
48. M. Fan and A. G. Brolo, 2008, “Self-assembled Au nanoparticles as substrates for surface-enhanced vibrational spectroscopy: Optimization and electrochemical stability”, ChemPhysChem, 9, 1899 – 1907. - Reprint - PDF
47. A. G. Brolo, R. Gordon, K. L. Kavanagh, 2008 “A new generation of sensors based on extraordinary light transmission”, invited review – Accounts of Chemical Research, 41, 1049-1057. Reprint - PDF
46 D. Sinton, R. Gordon and A. G. Brolo, 2008, "Nanohole Arrays in Metal Films as Optofluidic Elements: Progress and Potential", Microfluidics and Nanofluidics, 4, 107 – 116. Reprint - PDF
2007 45. J. R. Anema and A. G. Brolo, (2007), "The Use of Polarization-Dependent SERS from Scratched Au Surfaces to Selectively Eliminate Solution-Phase Interference", Plasmonics, accepted - Reprint- PDF
44. E. Kjeang, A. G. Brolo, D. A. Harrington, N. Djiali and D. Sinton, (2007), "Hydrogen Peroxide as an oxidant for a Microfluidic Fuel Cell", Journal of the Electrochemical Society, 154, B1220 - B1226. Reprint-PDF
43. M. J. L. Santos, A. G. Brolo and E. M. Girotto, (2007), "Study of polaron and bipolaron states in polypyrrole by in situ Raman spectroelectrochemistry", Electrochimica Acta, 52, 6141-6145 - Reprint - PDF 42. A. De Leebeeck, L. K. S. Kumar, V. de Lange, D. Sinton, R. Gordon, A. G. Brolo, (2007), “On-Chip Surface-Based Detection with Nano-Hole Arrays”, Analytical Chemistry, 79, 4094 - 4100 - Reprint - PDF
41. H. Yusuf, W.-G. Kim, D. H. Lee, M. Aloshyna, A. G. Brolo, and M. G. Moffitt, (2007), “A Hierarchical Self-Assembly Route to Polymer-Quantum Dot Photonic Arrays” Langmuir, 23, 5251-5254. - Reprint - PDF
40. E. Kjeang, B. T. Proctor, A. G. Brolo, D. A. Harrington, N. Djilali and D. Sinton , (2007), "High-Performance Microfluidic Vanadium Redox Fuel Cell", Electrochim. Acta, 52, 4942 - 4946 - Reprint - PDF
39. M. Aloshyna, A. G. Brolo, S. Sivakumar, M. Venkataramanan, and F. C. J. M. van Veggel, (2007), “Modification of spontaneous emission of Tb3+ ions incorporated in photonic crystals”, J. Phys. Chem. C. 111, 4047-4051 - Reprint - PDF
38. J.-H. Jin and A. G. Brolo, (2007), “Protoporphyrin-modified Au Thin Films Electrodes for Selective Monitoring of Catecholamines”– Electrochim. Acta - 52, 3863 - 3869 - Reprint - PDF 37. A. Lesuffleur, L. K. S. Kumar, A. G. Brolo, K. L. Kavanagh, R. Gordon, (2007), “Apex-enhanced Raman spectroscopy using double-hole arrays in a gold film”, J. Phys. Chem. C -111, 2347 - 2350 -Reprint - PDF
2006
35. C. J. Addison and A. G. Brolo, (2006), “Nanoparticle-containing Multilayer as a Substrate in Surface-Enhanced Raman Scattering (SERS)”, Langmuir,22, 8696 - 8702. -Reprint - PDF
34. G. Bussière, M. Musa, J. Hepburn, P.R. Norton, K. Griffiths and A. G. Brolo, (2006), “Dynamics of D2 Released from the Dissociation of D2O on a Zirconium Surface”, J. Chem. Phys., 124, 124704 - Reprint - PDF 33. A. G. Brolo, S. C. Kwok, M. D. Cooper, M. G. Moffitt, C.-W. Wang, R. Gordon, J. Riordon and K. L. Kavanagh, (2006), “Surface Plasmon–Quantum Dot Coupling from Arrays of Nanoholes.”, J. Phys. Chem. B., 110, 8307-8313 - Reprint - PDF
32. R. Gordon, L. K. S. Kumar and A. G. Brolo, (2006), “Resonant Light Transmission through a Nanohole in a Metal Film”, IEEE Transactions on Nanotechnology,5, 291-294. Reprint - PDF
2005 31. A. G. Brolo, S. C. Kwok, M. G. Moffitt, R. Gordon, J. Riordon, K. L. Kavanagh, (2005), "Enhanced Fluorescence from Arrays of Nanoholes in a Gold Film", J. Am. Chem. Soc., 127, 14936-14941. Reprint - PDF
30. R. Gordon, M. Hughes, B. Leathem, K. L. Kavanagh, A. G. Brolo, (2005), "Basis and Lattice Polarization Mechanisms for Light Transmission Through Nanohole Arrays in Metal Films", NanoLetters,5, 1243 - 1246. Reprint - PDF
29. A. G. Brolo, and C. J. Addison, (2005). “Surface-enhanced Raman Scattering from Oxazine 720 Adsorbed on Scratched Gold Films”. J. Raman. Spectrosc., 36, 629 - 634 (Special issue on SERS). - Reprint - PDF 28. R. Gordon and A. G. Brolo (2005). "Increased Cut-Off Wavelength for a Subwavelength Hole in a Real Metal". Optics Express, 13, 1933-1938 - Reprint - PDF 27. A. G. Brolo, E. Arctander and C. J. Addison, (2005). “Strong Polarized Enhanced-Raman Scattering via Optical Tunneling through Random Parallel Nanostructures in Au Thin Films”. J. Phys. Chem. B, 109, 401 - 405 - Reprint - PDF
2004 26. A. G. Brolo, E. Arctander, R. Gordon, B. Leathem and K. L. Kavanah, (2004). “Nanohole-Enhanced Raman scattering”. NanoLetters, 4, 2015 - 2018 - Reprint - PDF
25. A. G. Brolo and A. C. Sanderson, (2004). "Surface enhanced Raman scattering (SERS) from a silver electrode modified with oxazine 720". Canadian Journal of Chemistry, 82, 1474 - 1480. Reprint - PDF (Special Don Irish issue of Can J Chem). 24. A. G. Brolo, R. Gordon, B. Leathem and K. L. Kavanah, (2004). “Surface Plasmon Sensor Based on the Enhanced Light Transmission through Arrays of Nanoholes in Gold Films”. Langmuir, 20, 4813 - 4815 - Reprint -PDF
23. A.G. Brolo and Y. Yang (2004). “Exploring mechanisms of anodic film formation by electrochemical probe beam deflection (EPBD)”. Electrochimica Acta – 48, 1375 - 1384 - Reprint - PDF. 22. R. Gordon, A. G. Brolo, A. McKinnon, A. Rajora, B. Leathem and K. L. Kavanah, (2004). “Strong Optical Polarization via Elliptical Nano-holes”. Physical Review Letters, 92, 037401 (paper selected for publication in the Virtual Journal of Nanoscale Science & Technology-February 9, 2004 (http://www.vjnano.org/nano/)) -Reprint - PDF. 21. A. G. Brolo, A. C. Sanderson and A. P. Smith, (2004). "Ratio of the Surface-Enhanced Stokes to the Surface-Enhanced Anti-Stokes Scattering for Molecules Adsorbed on a Silver Electrode". Physical Review B, 69, 045424 - Reprint - PDF (paper selected for publication in the February 1st., 2004 issue of the Virtual Journal of Biological Physics Research (http://www.vjbio.org)). 2003 20. A. G. Brolo, Z. Jiang and D. E. Irish, (2003). "The orientation of 2,2' bipyridine adsorbed on a SERS active Au(111) surface". Journal of Electroanalytical Chemistry - 547 , 163 - 172 - Reprint - PDF. 19. G. Hager and A. G. Brolo, (2003) . "Adsorption/Desorption Behaviour of Cysteine and Cystine in Neutral and Basic Media: Electrochemical Evidence for Differing Thiol and Disulfide Adsorption to a Au(111) Single-Crystal Electrode". Journal of Electroanalytical Chemistry, 550-551C, 291-301. Reprint - PDF 18. A. G. Brolo and S. D. Sharma, (2003) . "Using Probe Beam Deflection (PBD) to Investigate the Electrochemical Oxidation of Silver in Chloride Media". Electrochimica Acta - 48, 1375-1384. - Reprint - PDF 2002 17. A. G. Brolo, P. Germain and G. Hager, (2002). “The Investigation of the Adsorption of L-Cysteine on a Polycrystalline Silver Electrode by Surface-Enhanced Raman Scattering (SERS) and Surface-Enhanced Second Harmonic Generation (SESHG)”. Journal of Physical Chemistry B, 106, 5982-5987. - Reprint - PDF 16. A. G. Brolo, M. Odziemkowski, J. Porter and D. E. Irish, (2002). “In Situ Micro Raman Investigation of Electrochemically Formed Films on Mercury Electrodes”.Journal of Raman Spectroscopy , 33, 136-141. - Reprint - PDF Publications before joining the University of Victoria
15. F. Bensebaa, Y. Zhou, A. G. Brolo, D. E. Irish, Y. Deslandes, E. Kruus and T. H. Ellis, (1999) “Raman Characterization of Metal-Alkanethiolates”, Spectrochimica Acta Part A , 55, 1229-1236 - Reprint - PDF 14. A. G. Brolo, M. Odziemkowski and D. E. Irish, (1998) “An In Situ Spectroscopic Study of Electrochemical Processes at Mercury/Solution Interphases”, Journal of Raman Spectroscopy , 29, 713 - 719. Reprint - PDF 13. A. G. Brolo, M.L.A. Temperini, S.M.L. Agostinho, (1998) “Copper Dissolution in Bromide Medium in the Absence and Presence of Hexamethylenetetramine (HMTA): Voltammetric and Chronoamperometric Studies”, Electrochimica Acta,44 , 559-571. - Reprint - PDF 12. A.G.Brolo, D.E. Irish, G. Szymanski and J. Lipkowski, (1998) “The Relationship Between SERS Intensity and Both Surface Coverage and Morphology for Pyrazine Adsorbed on a Polycrystalline Gold Electrode”, Langmuir, 14: 517 - 527.- Reprint - PDF 11. A. G. Brolo and D.E.Irish, (1997) “SERS Studies of Monoprotonated Pyrazine on Positively Charged Silver Electrodes”, Canadian Journal of Chemistry , 75 : 1643 - 1648 - Reprint - PDF 10. A. Iannelli, A. G. Brolo, D. E. Irish and J. Lipkowski, (1997) “Electrochemical and Raman Spectroscopic Studies of Pyrazine Adsorption at the Au(210) Electrode Surface”, Canadian Journal of Chemistry, 75: 1694 - 1702 - Reprint - PDF. 9. A. G. Brolo, D.E. Irish and J. Lipkowski, (1997), “Surface-Enhanced Raman Spectra of Pyridine and Pyrazine Adsorbed on a Au(210) Single-Crystal Electrode”, Journal of Physical Chemistry B, 101: 3906 - 3909 - Reprint - PDF. 8. A. G. Brolo, D. E. Irish and B. D. Smith, (1997), "Applications of Surface Enhanced Raman Scattering to the Study of Metal-Adsorbate Interactions", Journal of Molecular Structure , 405: 29-44. (review article) - Reprint - PDF. 7. A. G. Brolo and D. E. Irish, (1997) , "A SERS Study of the Electrochemical Reduction of Pyrazine on a Silver Electrode", Journal of the Chemical Society, Faraday Transactions , 93 : 419-425.Reprint - PDF 6. A. G. Brolo and D. E. Irish, (1997) , "The Behaviour of Pyrazine and Monoprotonated Pyrazine Adsorbed on Silver Electrodes: A Surface-Enhanced Raman Scattering Study", in Solid-Liquid Electrochemical Interfaces, G. Jerkiewicz, M. P. Soriaga, K. Closaki and A. Wieckowski, eds., ACS Symposium Series No 656, ACS, Washington, DC, Ch. 22: 310-322. 5. A. G. Brolo and D. E. Irish, (1996) , "Adsorption and Orientation of Pyrazine on Silver Electrode: A SERS Study", Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, 414: 183-196. Reprint - PDF 4. A. G. Brolo and D. E. Irish, (1995) , "Raman Spectral Studies of Aqueous Acidic pyrazine Solutions", Zeitschrift fur Naturforshung, 50a: 274-282. Reprint - PDF 3. A. G. Brolo, M. L. A. Temperini, S. M. L. Agostinho, (1992), "Effect of Hexamethylenetetramine as a Corrosion Inhibitor for Copper in Bromide Medium", Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, 335: 83-92. 2. The Brazilian Chemistry in Action Group, (1991), “Picturing the Chemical Relevance", Journal of Chemical Education, 68: 652-654. 1. A. G. Brolo, A. L. M. L. Mateus, M. A. Leme, (1989), "The Iodine Clock Reaction: A Surprising Variant", Journal of Chemical Education, 66: 852.
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